Correlated Mapping of Raman Spectroscopy and Cathodoluminescence of Emerging Absorber Bournonite (CuPbSbS3) [* Cross-Reference *]

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Oliver M Rigby; Chris Hill; Gunnar Kusch; Martin Naylor; Maël Guennou; Guillaume Zoppi; Marek Szablewski; Rachel A. Oliver; Ludger Wirtz; Phillip J. Dale; Budhika G. Mendis, 2023, "Correlated Mapping of Raman Spectroscopy and Cathodoluminescence of Emerging Absorber Bournonite (CuPbSbS3) [* Cross-Reference *]", https://lore.list.lu/citation?persistentId=perma:LIST.ILPEVF, LIST Open Repository, V1

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Description	Bournonite (CuPbSbS3) is an emerging absorber material for solar cells. There is little literature on some of its fundamental structural and optical properties. We report the first complete Raman spectra of bournonite as well as the first luminescence signal. A chosen area has been mapped with both Raman spectra and cathodoluminescence (CL) to investigate the structural and optical uniformity. Raman mapping reveals a new secondary phase, tetrahedrite, but otherwise a uniform compositional thin-film. CL mapping reveals slight redshift at grain boundaries (GBs). Preliminary devices made with a bournonite absorber layer show rectification under standard test conditions. (2023-06-11) *This entry has been automatically imported via OpenAlex by LIST harvest scripts. Please refer to https://doi.org/10.1109/pvsc48320.2023.10360067 for the original and latest version of the publication* (2026-07-01)
Subject	Engineering; Physics
Keyword	Cathodoluminescence, Raman spectroscopy, Materials science, Luminescence, Optoelectronics, Grain boundary, Spectroscopy, Analytical Chemistry (journal), Optics, Chemistry, Microstructure, Physics, Composite material
License/Data Use Agreement	Custom Dataset Terms


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Persistent Identifier	perma:LIST.ILPEVF
Publication Date	2026-07-06
Title	Correlated Mapping of Raman Spectroscopy and Cathodoluminescence of Emerging Absorber Bournonite (CuPbSbS3) [* Cross-Reference *]
Other Identifier	https://doi.org/10.1109/pvsc48320.2023.10360067 OpenAlex ID: https://openalex.org/W4390189158
Author	(University of Luxembourg, Durham University, University of Cambridge, Northumbria University, Luxembourg Institute of Science and Technology)https://orcid.org/0000-0003-3559-2125 (University of Luxembourg, Durham University, University of Cambridge, Northumbria University, Luxembourg Institute of Science and Technology)https://orcid.org/0000-0002-6914-4411 (University of Luxembourg, Durham University, University of Cambridge, Northumbria University, Luxembourg Institute of Science and Technology)https://orcid.org/0000-0003-2743-1022 Martin Naylor (University of Luxembourg, Durham University, University of Cambridge, Northumbria University, Luxembourg Institute of Science and Technology) (University of Luxembourg, Durham University, University of Cambridge, Northumbria University, Luxembourg Institute of Science and Technology)https://orcid.org/0000-0001-9349-3024 (University of Luxembourg, Durham University, University of Cambridge, Northumbria University, Luxembourg Institute of Science and Technology)https://orcid.org/0000-0003-3622-6899 (University of Luxembourg, Durham University, University of Cambridge, Northumbria University, Luxembourg Institute of Science and Technology)https://orcid.org/0000-0001-6694-140X (University of Luxembourg, Durham University, University of Cambridge, Northumbria University, Luxembourg Institute of Science and Technology)https://orcid.org/0000-0003-0029-3993 (University of Luxembourg, Durham University, University of Cambridge, Northumbria University, Luxembourg Institute of Science and Technology)https://orcid.org/0000-0001-5618-3465 (University of Luxembourg, Durham University, University of Cambridge, Northumbria University, Luxembourg Institute of Science and Technology)https://orcid.org/0000-0003-4821-8669 (University of Luxembourg, Durham University, University of Cambridge, Northumbria University, Luxembourg Institute of Science and Technology)https://orcid.org/0000-0003-2334-2866
Point of Contact	Use email button above to contact. LIST QDKM (LIST)
Description	Bournonite (CuPbSbS3) is an emerging absorber material for solar cells. There is little literature on some of its fundamental structural and optical properties. We report the first complete Raman spectra of bournonite as well as the first luminescence signal. A chosen area has been mapped with both Raman spectra and cathodoluminescence (CL) to investigate the structural and optical uniformity. Raman mapping reveals a new secondary phase, tetrahedrite, but otherwise a uniform compositional thin-film. CL mapping reveals slight redshift at grain boundaries (GBs). Preliminary devices made with a bournonite absorber layer show rectification under standard test conditions. (2023-06-11) *This entry has been automatically imported via OpenAlex by LIST harvest scripts. Please refer to https://doi.org/10.1109/pvsc48320.2023.10360067 for the original and latest version of the publication* (2026-07-01)
Subject	Engineering; Physics
Keyword	Cathodoluminescence Raman spectroscopy Materials science Luminescence Optoelectronics Grain boundary Spectroscopy Analytical Chemistry (journal) Optics Chemistry Microstructure Physics Composite material
Topic Classification	Chalcogenide Semiconductor Thin Films Quantum Dots Synthesis And Properties Advanced Semiconductor Detectors and Materials
Deposit Date	2023-06-11
Data Type	Article

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