|
Persistent Identifier
|
perma:LIST.IL4KDB |
|
Publication Date
|
2026-07-06 |
|
Title
| Tuning structural isomers of phenylenediammonium to afford efficient and stable perovskite solar cells and modules [* Cross-Reference *] |
|
Other Identifier
| https://doi.org/10.1038/s41467-021-26754-2
SCOPUS_ID:85118627290 |
|
Author
| Liu, Cheng (North China Electric Power University, Institute of Chemical Sciences and Engineering) - ORCID: 0000-0003-0258-4428
Yang, Yi (North China Electric Power University, Institute of Chemical Sciences and Engineering) - ORCID: 0000-0002-7775-6856
Rakstys, Kasparas (Kaunas University of Technology) - ORCID: 0000-0001-8016-9567
Mahata, Arup (Istituto Italiano di Tecnologia, Consiglio Nazionale delle Ricerche) - ORCID: 0000-0002-4995-3326
Franckevicius, Marius (Fizinių ir Technologijos Mokslų Centras)
Mosconi, Edoardo (Consiglio Nazionale delle Ricerche)
Skackauskaite, Raminta (Kaunas University of Technology)
Ding, Bin (Institute of Chemical Sciences and Engineering)
Brooks, Keith G. (Institute of Chemical Sciences and Engineering)
Usiobo, Onovbaramwen Jennifer (Luxembourg Institute of Science and Technology)
Audinot, Jean Nicolas (Luxembourg Institute of Science and Technology)
Kanda, Hiroyuki (Institute of Chemical Sciences and Engineering)
Driukas, Simonas (Fizinių ir Technologijos Mokslų Centras)
Kavaliauskaite, Gabriele (Fizinių ir Technologijos Mokslų Centras)
Gulbinas, Vidmantas (Fizinių ir Technologijos Mokslų Centras)
Dessimoz, Marc (Institute of Chemical Sciences and Engineering)
Getautis, Vytautas (Kaunas University of Technology)
De Angelis, Filippo (Istituto Italiano di Tecnologia, Università degli Studi di Perugia, Prince Mohammad Bin Fahd University)
Ding, Yong (North China Electric Power University, Institute of Chemical Sciences and Engineering) - ORCID: 0000-0002-4921-0979
Dai, Songyuan (North China Electric Power University) - ORCID: 0000-0001-5710-9208
Dyson, Paul J. (Institute of Chemical Sciences and Engineering) - ORCID: 0000-0003-3117-3249
Nazeeruddin, Mohammad Khaja (Institute of Chemical Sciences and Engineering, City University of Hong Kong) - ORCID: 0000-0001-5955-4786 |
|
Point of Contact
|
Use email button above to contact.
LIST RDS (LIST) |
|
Description
| Organic halide salt passivation is considered to be an essential strategy to reduce defects in state-of-the-art perovskite solar cells (PSCs). This strategy, however, suffers from the inevitable formation of in-plane favored two-dimensional (2D) perovskite layers with impaired charge transport, especially under thermal conditions, impeding photovoltaic performance and device scale-up. To overcome this limitation, we studied the energy barrier of 2D perovskite formation from ortho-, meta- and para-isomers of (phenylene)di(ethylammonium) iodide (PDEAI2) that were designed for tailored defect passivation. Treatment with the most sterically hindered ortho-isomer not only prevents the formation of surficial 2D perovskite film, even at elevated temperatures, but also maximizes the passivation effect on both shallow- and deep-level defects. The ensuing PSCs achieve an efficiency of 23.9% with long-term operational stability (over 1000 h). Importantly, a record efficiency of 21.4% for the perovskite module with an active area of 26 cm2 was achieved. (2021-12-01)
***This entry has been automatically imported via Infodoc(ASO) CSV by LIST harvest scripts. Please refer to https://doi.org/10.1038/s41467-021-26754-2 for the original and latest version of the dataset and data downloads*** (2026-06-12) |
|
Subject
| Physics |
|
Keyword
| Organic halide salt
perovskite solar cells
halide salt passivation
Organic halide
solar cells |
|
Funding Information
| Horizon 2020 Framework Programme: 763977 |
|
Deposit Date
| 2021-12-01 |
|
Data Type
| Article |
|
Data Source
| Nature Communications; eISSN: 20411723, vol. 12, n° 1, art. no. 6394 |